黄光许, 刘迎宾, 耿乾浩, 等. 低黏结剂配比下无烟煤的成型与机理[J]. 煤炭学报, 2019, 44(S1): 289-295. DOI: 10.13225/j.cnki.jccs.2018.1167
引用本文: 黄光许, 刘迎宾, 耿乾浩, 等. 低黏结剂配比下无烟煤的成型与机理[J]. 煤炭学报, 2019, 44(S1): 289-295. DOI: 10.13225/j.cnki.jccs.2018.1167
HUANG Guangxu, LIU Yingbin, GENG Qianhao, et al. Briquetting and its mechanism of anthracite under low mass ration of binder[J]. Journal of China Coal Society, 2019, 44(S1): 289-295. DOI: 10.13225/j.cnki.jccs.2018.1167
Citation: HUANG Guangxu, LIU Yingbin, GENG Qianhao, et al. Briquetting and its mechanism of anthracite under low mass ration of binder[J]. Journal of China Coal Society, 2019, 44(S1): 289-295. DOI: 10.13225/j.cnki.jccs.2018.1167

低黏结剂配比下无烟煤的成型与机理

Briquetting and its mechanism of anthracite under low mass ration of binder

  • 摘要: 无烟煤型煤具有一定粒度和冷热强度,可部分替代块煤用于合成氨造气。晋城无烟块煤是优质的合成氨气化原料,但储量有限,进行晋城无烟煤粉煤成型研究意义重大。本文采取单因素实验方法,以晋城无烟粉煤为原煤,自制改性生物质、膨润土为黏结剂,配入少量添加剂混合,利用手工模具加压成型; 测定所制型煤样品的冷强度和热强度,探究不同黏结剂组分和添加剂配比对型煤强度性能的影响规律; 利用红外光谱(FTIR),X射线衍射(XRD)和扫描电子显微镜(SEM)等技术手段研究型煤的成型机理。结果表明:随着改性生物质添加量的增大或添加剂溶液浓度的增大(体积不变),型煤样品的冷强度和热强度均呈现先增大后降低的趋势; 而随着膨润土添加量的增大,型煤的冷强度和热强度均呈现增大趋势。本研究中晋城无烟煤型煤制备的工艺配方为无烟煤95.3%,改性生物质1.5%,膨润土3%,添加剂0.2%。相应型煤样品的冷强度为589 N/球,热强度为220 N/球,煤质分析与原煤相比变化不大,各项理化指标完全满足工业储运和气化要求。添加剂有助于改性生物质部分水解生成小分子化合物及其他物质,同时将原煤中所含的二氧化硅转化为硅酸钠等物质,提高煤与黏结剂的黏结效果。原料煤煤粒、膨润土和改性生物质等各组分之间紧密结合,使型煤成为具有一定强度的整体。本文所述的型煤制备工艺配方中黏结剂的添加量较低(< 5%),黏结剂成本低廉; 型煤样品的理化指标达到或超过现有技术水平,应用前景广阔。

     

    Abstract: Anthracite briquette, possessing certain particle size, cold strength and ther-mal strength, can partially replace lump coal for gasification in ammonia synthesis.Shanxi anthracite is high-quality raw material for coal gasification, and the related stud-ies are of great significance because of the limited resource reserves.Herein, using Shanxi anthracite powder as the raw material, the briquettes were prepared using a manual briquetting machine based on the binders of modified biomass and bentonite as well as small amount of additive.The influence of the binder ratio on the briquette properties was investigated according to the cold strength and thermal strength of as-prepared briquettes.The corresponding briquetting mechanism was also studied by infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron micros-copy (SEM).The results indicate that with the increase of the additive amount of modi-fied biomass or additive solution concentration, the cold strength and thermal strength of as-prepared briquettes both increase first and then decrease, which will increase with the additive amount of bentonite.The optimal process parameters of briquette were de-termined as follows:anthracite 95.3%, modified biomass 1.5%, bentonite 3%, additive 0.2%.The as-prepared briquette exhibits a cold strength of 589 N/ball and a thermal strength of 220 N/ball, with the similar coal analysis results to the raw coal, and its physicochemical properties can meet the gasification requirements.The additive cannot only help to partially hydrolyze the biomass to generate small molecular compounds and other substances, but also convert the silicon oxide in the coal into sodium silicate, resulting in an improvement of the bonding effect between the coal particles and the binders.Large coal particles in the briquette are surrounded and fixed by small coal par-ticles, binders and the additive.Noticeably, the additive amount of briquette binder is less than 5%, the production cost is approximately 30 Chinese yuan per ton of briquette, which is superior to that reported in the literature and in the industrial production.

     

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