鱼卡凹陷石门沟组上段泥页岩地球化学及储层特征

Geochemistry and reservoir characteristics of shale in the upper member of Shimengou Formation,Yuka sag

  • 摘要: 鱼卡凹陷位于柴达木盆地北缘中部,为青海省陆相页岩气勘探的重点区域。中侏罗统石门沟组上段为半深湖-深湖相沉积,暗色泥页岩厚度10~170 m,平均为55 m;为页岩气勘探的主力层系。运用液氮吸附、有机碳含量、有机质成熟度、干酪根元素、全岩、黏土矿物X衍射、能谱扫描电镜等测试方法,对泥页岩样品的有机地球化学及储层特征进行了研究,结果表明:中侏罗统石门沟组泥页岩TOC含量为1.34%~12.84%,均值为5.3%;干酪根H/C和O/C比范式图解上显示有机质类型主要为Ⅱ2型;Ro为0.45%~1.00%,总体热成熟度表现为凹陷西部高于东部。黏土矿物含量为34%~58%,平均46.1%;石英含量42%~55%,平均48.3%。泥页岩孔隙结构复杂,根据吸附回线及孔径分布曲线划分为两类:第1类以一端不透气性孔和四边开放的板状狭缝孔为主,孔径主要集中在3~5 nm,呈单峰状分布;第2类以一端不透气性孔和开放性倾斜板狭缝孔为主,孔径主要分布在3~5 nm和6~45 nm,呈双峰状分布。由于泥页岩成熟度较低,有机质纳米孔隙不发育,TOC含量与介孔、总孔体积具有弱正相关性,与微孔体积相关性不大;脆性矿物含量与孔隙度成正相关,黏土矿物含量与微孔体积相关性不大,与介孔、总孔体积呈正相关。黏土矿物是石门沟组上段泥页岩纳米孔隙的主要提供者,是孔隙发育的主要控制因素;孔隙结构及孔径分布和沉积环境有关,TOC含量及热演化程度也会影响泥页岩孔隙发育的程度。

     

    Abstract: Yuka sag,located in the middle of the north margin of Qaidam basin,is a key area for continental shale gas exploration in Qinghai province. The upper member of the Shimengou formation of the middle Jurassic is a semi-deep lacustrine to deep lacustrine facies deposit with a dark shale thickness of 10-170 m with an average of 55 m for major formation in shale gas exploration. The organic geochemistry and reservoir characteristics were studied by using nitrogen gas adsorption,total organic carbon content,organic matter maturity,kerogen element,X-ray diffraction analyses and SEM. The results show that the TOC content in Shimengou formation of middle Jurassic is 1. 34% -12. 84% ,with an average of 5. 3% . Kerogen types are mainly type Ⅱ2 ;Ro ranges from 0. 45% to 1. 0% ,which is higher in the west- ern area than that in the eastern area. Clay mineral content ranges from 34% to 58% with an average of 46. 1% . Quartz content ranges from 42% to 55% ,with an average of 48. 3% . The nanopore structure in the Shimengou shale are complex,which can be divided into two types according to the nitrogen adsorption-desorption curves and pore di- ameter distribution. The first type is dominated by the airtight pores with one end closed and the open parallel plate-slit pores,and the pore diameters are in a range of 3-5 nm with a single-peak distribution. The second type mainly con- sists of the airtight pores with one end closed and open inclined slit pores,peaking in a range of 3-5 nm and 6-45 nm with a bimodal distribution. Due to the low maturity,the nano pores of organic matter are not developed,TOC content has a weak positive correlation with mesoporous and total pore volume,but not with micropore volume. Brittle mineral content is positively correlated with porosity,clay mineral content is not correlated with micropore volume,but positive- ly correlated with mesoporous volume and total pore volume. The clay content is a key factor controlling the nanopore development in shale,the pore structure and pore diameter distribution are related to sedimentary environment,and the TOC content and thermal evolution also have some influence.

     

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