孔隙结构对煤质脱硫脱硝活性焦机械强度影响

Effect of pore structure on mechanical strength of coal-based activated coke for desulfurization and denitration

  • 摘要: 发达的孔隙结构是降低煤质脱硫脱硝用活性焦机械强度的重要原因,严重缩短活性焦循环使用寿命。以8种新鲜活性焦、3种固定床循环使用不同次数活性焦、1种流动床净化系统循环使用的活性焦为原料,通过对各活性焦试样机械强度指标、气孔特征指标的检测和对耐压强度、耐磨强度与气孔开闭状态、孔径分布的相关性研究,明确循环使用过程中活性焦孔隙结构和机械强度的变化规律及活性焦孔隙结构对机械强度的影响规律。结果表明:由于热再生过程中硫酸分解对活性焦的活化作用,随循环使用次数的增加各孔径范围的开气孔均得到进一步发展,进而导致耐压强度和耐磨强度不断下降。与新鲜活性焦相比,流动床净化系统中循环使用的活性焦0~2,2~500,大于500 nm区间的气孔孔容分别上升45.3%,50.5%,5.5%,耐压强度约为新鲜活性焦的70%,耐磨强度高于新鲜活性焦1.7%。开气孔是降低活性焦耐压强度的主要气孔类型,孔径在2~500 nm的开气孔对耐压强度的破坏作用最为显著,该孔径区间的气孔孔容每升高0.01 cm3/g,耐压强度降低38.704 N,新鲜活性焦、固定床和流动床循环使用后活性焦的耐压强度随2~500 nm气孔孔容的变化均满足此线性变化规律。开气孔和闭气孔对耐磨强度的破坏作用程度无明显差异,孔径在0~2 nm的气孔对耐磨强度的破坏最为显著,该孔径区间的气孔孔容每升高0.01 cm3/g,耐磨强度降低1.796 9%,新鲜活性焦和固定床循环使用后活性焦的耐磨强度随0~2 nm气孔孔容的变化满足此线性变化规律,而流动床净化系统使用的活性焦经磨损后颗粒表面较为光滑,耐磨强度明显高于该变化规律。

     

    Abstract: The developed pore structure is an important reason for reducing the mechanical strength of coal-based activated coke for desulfurization and denitrification, which seriously shortens its service life.The eight fresh activated cokes (Fresh-AC), three activated cokes recycled by fixed bed different times (Fixed-AC), and one activated coke recycled by fluidized bed purifi-cation system (Fluidized-AC) were investigated.The mechanical strength index, stomatal charac-teristic index of activated coke samples were measured, and the correlations between compressive strength, abrasion resistance and pore opening-closing state, pore size distribution were analyzed.Then, the variation law of pore structure and mechanical strength of activated coke during recycling and the influence of pore structure on mechanical strength were clarified.The results show that the activated coke open pores in all pore size are further developed with the increase of the cycles number because of the activation effect from sulfuric acid decomposition on activated coke during thermal regeneration, and then the compressive strength and abrasion resistance continue to decrease accordingly.Compared with Fresh-AC, the 0-2 nm, 2-500 nm, and larger than 500 nm pore volume of Fluidized-AC increase by 45.3%, 50.5%, 5.5%, respectively, the strength is only about 70% of Fresh-AC, and the abrasion resistance is 1.7% higher than Fresh-AC.The open pore is the main pore type that reduces activated coke compressive strength.The 2-500 nm open pore has the greatest damage to compressive strength.For each increase of 2-500 nm pore volume of 0.01 cm3/g, the compressive strength decreases by 38.704 N.The compressive strength of Fresh-AC, Fixed-AC, Fluidized-AC all abide by this linear variation law with the change of 2-500 nm pore volume.There is no significant difference in the damage degree of the abrasion resistance between the open pore and the closed pore.The 0-2 nm pore has the most significant damage to abrasion resistance.For each increase of 0-2 nm pore volume of 0.01 cm3/g, the abrasion strength decreases by 1.769 9%.The abrasion resistance of Fresh-AC and Fixed-AC obey by this linear variation law with the change of 0-2 nm pore volume, yet the abrasion resistance of Fluidized-AC is significantly higher than this linear variation law because of its smoother particle surface.

     

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