不同脱气温度下低阶煤孔隙结构特征——以新疆吐哈盆地西山窑组褐煤为例
Pore structure characteristics of low-rank coal under various degassing temperatures: A case study of lignite from Xishanyao Formation, Turpan-Hami Basin, Xinjiang
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摘要: 在开展低温氮气吸附实验时,样品脱气温度对低阶煤孔隙结构具有显著的影响,而适宜的低阶煤脱气温度尚无明确定论。对采集自新疆吐哈盆地的低阶煤样使用TriStar II Plus Series比表面与孔隙度分析仪,以30℃为步长,开展120~300℃不同脱气温度下的低阶煤样孔隙结构试验测试。结果表明:煤样质量随脱气温度的升高持续下降,在煤样脱气温度≤180℃时,煤样质量减少较为缓慢,随后煤样质量减少率有所增加,尤其是在脱气温度≥240℃时,煤样质量快速下降,这与高温作用下低阶煤样中挥发分的快速析出作用有关;随脱气温度的升高,煤样吸附/解吸滞后环呈逐渐减小的趋势,且在相对压力0.5时脱附曲线的拐点逐渐减小至消失,表明低阶煤样孔隙结构发生变化,且孔隙结构由复杂变的简单;随脱气温度的逐渐升高,煤岩的氮气最大吸附量和煤岩孔容呈现出三段式变化,煤岩孔比表面积则持续下降,这与升温过程中低阶煤样中部分孔隙热作用下的孔隙坍塌作用相关;煤岩阶段孔容和阶段孔比表面积随脱气温度的升高而持续下降,但其主要发生在孔径<20 nm的孔隙范围内,表明微孔和孔径<20 nm的介孔孔隙的坍塌作用对煤岩孔容和孔比表面积的控制作用显著,而由于孔径<20 nm孔隙的坍塌作用,微孔和部分介孔转变为更大孔径的介孔和大孔,低阶煤样的平均孔径呈逐渐增大的趋势。较高的脱气温度下,挥发分的析出作用及孔隙坍塌作用表明低阶煤孔隙结构已经失真,而在脱气温度≤150℃时,煤岩累积孔容和累积孔比表面积曲线差异最小,煤岩孔隙结构较为一致,较低预处理温度下低阶煤样孔隙结构未发生显著改变。因此,在利用低温氮气吸附法开展低阶煤孔隙结构特征研究时,脱气温度以不超过150℃为佳。Abstract: The degassing temperature presents a significant influence on the pore structure of the low-rank coal when the low-temperature nitrogen adsorption measurements are conducted, while the appropriate degassing temperature is still equivocal.Aiming this, the low-rank coal sample collected from Turpan-Hami Basin was used to make low-temperature nitrogen adsorption measurements, and the pore structure characteristics under various degassing temperatures were also investigated.The results show that the coal sample mass decreases continuously with the increased degassing temperatures.When the degassing temperature is lower than 180 ℃,the sample mass loss rate is slow, following that the sample mass loss rate tends to increase, especially when the degassing temperature exceeds 240 ℃,the massive evaporation of the volatiles would lead to the sharp decrease of the sample mass with the increased degassing temperature.When the degassing temperature increases, the hysteresis loops of the coal sample feature continuously decrease, and the knee points of the desorption branch at the relative pressure of 0.5 becomes weaken, indicating the various dynamic change of the pore structure, and the pore structure of the low-rank coal sample varies from complicated to simple.With the increased degassing temperatures, the maximum nitrogen adsorption quantities and the pore volume feature vary in three-step-style, while the pore specific surface area of the low-rank coal decreases, which is dominantly related to the sharply decomposition of the volatile matters in the low-rank coal under high degassing temperature.The continuously decrease of the incremental pore volume and pore specific surface area with the increased degassing temperatures mainly occur at the pores with the aperture below 20 nm, indicating the collapse of these pores contributed dominantly to the decrease of the pore volume and pore specific surface area.Due to the collapse of micropores and partly of mesopores, the pores with larger apertures tend to be concentrated, the average pore apertures present an increasing trend when compared with that of pore specific surface area with the increased degassing temperatures.With higher degassing temperature, due to the massive evaporation of the volatiles and the collapse of the pores, the pore structure has been reformed significantly.When the degassing temperature is lower than 150 ℃,the differences for the cumulative pore volumes and pore specific surface areas are least, indicating the pore structure still maintains.Therefore, the lower degassing temperature(≤150 ℃) would be an appropriate degassing temperature for the pore structure of the low-rank coal when the low-temperature nitrogen adsorption is used.