陈茂山, 李君, 孙凯蒂, 等. 液化油渣萃余物大规模气化行为[J]. 煤炭学报, 2022, 47(6): 2435-2445. DOI: 10.13225/j.cnki.jccs.2021.1060
引用本文: 陈茂山, 李君, 孙凯蒂, 等. 液化油渣萃余物大规模气化行为[J]. 煤炭学报, 2022, 47(6): 2435-2445. DOI: 10.13225/j.cnki.jccs.2021.1060
CHEN Maoshan, LI Jun, SUN Kaidi, et al. Large-scale gasification behavior of extraction residue of coal liquefaction residue[J]. Journal of China Coal Society, 2022, 47(6): 2435-2445. DOI: 10.13225/j.cnki.jccs.2021.1060
Citation: CHEN Maoshan, LI Jun, SUN Kaidi, et al. Large-scale gasification behavior of extraction residue of coal liquefaction residue[J]. Journal of China Coal Society, 2022, 47(6): 2435-2445. DOI: 10.13225/j.cnki.jccs.2021.1060

液化油渣萃余物大规模气化行为

Large-scale gasification behavior of extraction residue of coal liquefaction residue

  • 摘要: 煤液化油渣萃余物气化制氢既可有效解决油渣萃余物的处理问题,又可为煤直接液化装置提供所需的原料氢气,是实现液化油渣萃余物资源化利用的有效途径。针对液化油渣萃余物大规模气化应用中的关键问题,开展了液化油渣萃余物的气化反应活性、干粉输送特性及灰渣特性的相关研究,对液化油渣萃余物的干粉气化适应性进行了评估。在此基础上,依托国家能源投资集团低碳研究院3 t/d规模的密相输送和气化中试试验装置开展了相关中试试验研究,重点考察了其工艺稳定性、液态排渣情况、气化性能指标等,提出了液化油渣萃余物大规模气化的整体解决方案。最后,依据中试试验结果,运用数值模拟方法分析了在神华鄂尔多斯煤气化制氢装置进行萃余物掺烧对其气化性能的影响。结果表明,萃余物焦的气化反应活性优于煤焦,萃余物焦添加后,混合物焦的气化反应活性有所提升。当萃余物的含量不高于20%时,含萃余物混煤可在背压4 MPa、压差0.5 MPa、管径25 mm工况下稳定输送。当萃余物含量高于20%时,混煤的熔渣由玻璃渣转变为结晶渣,在气化过程中有堵渣风险。中试试验验证发现:掺混20%萃余物的混煤在中试装置中气化时,气化炉排渣口发生较为严重的堵渣现象,而当将萃余物掺混量降为10%时,气化过程排渣顺畅,因此建议工业装置掺烧萃余物的比例应控制在10%以下。同时,数值模拟结果也进一步表明,当气化原料中掺混10%萃余物时,对工业规模气化炉内温度场及组分分布无显著影响。

     

    Abstract: Gasification of extraction residue from coal liquefaction residue to produce hydrogen can effectively solve the disposal problem and provide the raw material hydrogen for coal direct liquefaction production plant, so as to realize the resource utilization and make full use of liquefaction residue.In this paper, a series of studies were conducted on the gasification reactivity, ash characteristics and dry powder transport characteristics of extraction residue from coal liquefaction residue.Gasification suitability was also evaluated.Based on the 3 t/d dense-phase transport and gasification pilot plant of China Energy Investment Corporation, some relevant pilot test researches were carried out, the process stability, liquid slag discharge phenomenon and gasification performance index were investigated.Moreover, based on the results of the pilot test, the effect of blending extraction residue in Shenhua Ordos coal gasification hydrogen production plant on its performance was simulated numerically.Results show that extraction residue coke exhibits a better gasification reactivity than coke does.When the content of extraction residue is lower than 20%, the raw material can be conveyed stably.Under the following conditions, that back pressure, pressure difference and pipe diameter are 4 MPa, 0.5 MPa and 25 mm, respectively.When its content exceeds 20%, the crystal structure of slag starts to crystallization, which may cause slag blockage problem in the gasification process.It was also confirmed in the pilot scale test, the serious blockage occurred at the slag outlet of gasifier when the content of extraction residue was 20%, and the gasification process was stable when the content of extraction residue was 10%.Therefore, in industrial process, the proportion of extraction residue should be controlled below 10%.The CFD analysis also shows that a 10% addition of extraction residue doesn’t have significant effect on the temperature field as well as their composition distribution.

     

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