Abstract: The changes in the landscape structure within resource-dependent urban areas is influenced by a confluence of factors, potentially resulting in a decreased landscape ecological quality and a heightened ecological vulnerability. Landscape ecological quality directly influences the flow and transmission of ecological functions, rendering it a pivotal consideration in the development of landscape ecological networks. In this study, an investigation was conducted utilizing land-use data spanning from 2005 to 2020, encompassing the city of Linfen in Shanxi Province, China. A landscape ecological risk assessment model was formulated to analyze the spatiotemporal attributes of landscape ecological risk during this timeframe. Acknowledging the underlying connection between ecosystem resilience and landscape ecological quality, the 2020 landscape ecological risk assessment served as the basis for the extraction of ecological source areas using the Minimum Spanning Tree with Path Algorithm (MSPA), and the corridors were established using the Minimum Cumulative Resistance (MCR) model. This framework facilitated the construction of a landscape ecological network, and the complex network analysis was employed to scrutinize the network’s topological properties. The regions within the study area exhibiting high and extremely high ecological risk displayed an initial increase followed by a subsequent decrease, culminating in an overall reduction in risk levels. The areas surrounding urban development and mining activities displayed relatively heightened risk levels, while the regions characterized by forests and grasslands experienced relatively lower risks. The shifts in risk within the study area were predominantly attributed to various factors, including mining activities, urban expansion, governmental policies, alterations in land-use types, and village migrations. Through the optimization of the landscape ecological network using edge addition strategies and a subsequent comparison of network robustness pre- and post-optimization, it was discerned that the edge addition strategy notably improved the efficiency of energy transfer and interconnectivity among network nodes. This ecological risk assessment model, in conjunction with the development of a prospective ecological network, lends a valuable theoretical support to the enhancement of landscape structure within resource-dependent urban areas and the establishment of comprehensive ecological security systems.