鄂尔多斯盆地延安组富油煤和含油煤生烃特征差异及其成因

Differences and origins of hydrocarbon generation characteristics between tar-rich coal and tar-containing coal in Yan’an Formation, Ordos Basin

  • 摘要: 富油煤的油气资源属性为立足国内增加油气供给提供了新的方向,生烃动力学特征是决定富油煤原位热解改质潜力和温度条件的关键因素,但富油煤与含油煤热解生烃特征差异及造成差异的成因尚不明确。以鄂尔多斯盆地黄陇侏罗系煤田延安组富油煤和含油煤为例,在2类煤生烃动力学特征、煤岩与煤质特征、地球化学特征分析的基础上,分析了富油煤和含油煤生烃特征差异性及有机、无机物质组成差异对2类煤生烃特征的影响。结果表明:鄂尔多斯盆地延安组富油煤和含油煤的有机质类型均为Ⅱ2型,整体处于低成熟阶段;富油煤有机显微组分中高的镜质组和类脂组含量使其生烃潜力明显高于含油煤。延安组富油煤的生烃活化能主频值(260~380 kJ/mol)相对较低且集中,生烃过程具有门限阈值低、转化周期短的特征;含油煤的生烃活化能主频值(330~470 kJ/mol)相对较高且离散,生烃过程具有门限阈值高、转化周期长的特征。延安组富油煤和含油煤的生烃过程及其特征受煤岩和煤质特征、古沉积环境和母质来源构成以及放射性元素的综合影响,富油煤和含油煤的生烃活化能主频值和分布的离散程度随有机显微组分中类脂组和镜质组含量的增大、沉积环境还原性的增强、母质来源中低等水生生物占比及陆源有机质中针叶树树脂含量的增大而降低,随有机显微组分中惰质组含量的增大、水分和黏土矿物含量的增大以及放射性元素铀、钍含量的增大而增大。

     

    Abstract: Properties of oil and gas resource found in tar-rich coal present a novel avenue for enhancing domestic oil and gas supply. The characteristics of hydrocarbon generation kinetics are critical factors that influence the in-situ pyrolysis conversion potential and the temperature conditions associated with tar-rich coal. Nevertheless, the distinctions in hydrocarbon generation processes and characteristics between tar-rich coal and tar-containing coal, as well as the underlying causes of these differences, remain inadequately understood. The hydrocarbon generation kinetics, coal rock and quality characteristics, and geochemical characteristics were carried out for investigating the differences and origins in hydrocarbon generation characteristics between tar-rich coal and tar-containing coal of Yan’an Formation from Huanglong Jurassic coalfield in Ordos Basin. The findings reveal that both tar-rich coal and tar-containing coal are classified as type Ⅱ2 kerogen and are generally characterized by low maturity. The elevated levels of vitrinite and liptodetrinite of tar-rich coal significantly enhance its hydrocarbon generation potential in comparison to tar-containing coal. The hydrocarbon generation activation energy (260-380 kJ/mol) of tar-rich coal is relatively low and concentrated, indicating a hydrocarbon generation process characterized by a low threshold and a short conversion cycle. In contrast, the hydrocarbon generation activation energy (330-470 kJ/mol) of tar-containing coal is higher and more dispersed, reflecting a hydrocarbon generation process with a high threshold and an extended conversion cycle. The hydrocarbon generation processes and characteristics of the tar-rich coal and tar-containing coal from Yan’an Formation are comprehensively influenced by factors such as coal rock and quality characteristics, paleo-sedimentary environments, parent material composition, and radioactive elements. The value and dispersion degree of activation energy for both tar-rich coal and tar-containing coal decrease with an increase in the content of vitrinite and liptodetrinite, enhanced reducibility within the sedimentary environment, a greater proportion of aquatic organisms in the composition of parent material and conifer resin in terrestrial organic matter. Conversely, the value and dispersion degree of activation energy increase with higher levels of inertinite content, water and clay mineral content, as well as elevated concentrations of radioactive elements such as uranium and thorium.

     

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