氧化/低阶煤浮选研究现状与展望

Status and prospects of oxidized/low rank coal flotation research

  • 摘要: 氧化/低阶煤浮选技术的研究进展对于提高煤炭资源的利用效率具有重要意义。综述氧化/低阶煤浮选技术的研究进展,探究氧化/低阶煤难以高效浮选的根本原因能够为开发新型高效氧化/低阶煤浮选技术与工艺提供依据。在分析氧化/低阶煤表面性质的基础上,总结了近年来国内外学者在氧化/低阶煤选前预处理、界面调控和浮选过程强化等方面的研究成果,并概述了目前氧化/低阶煤浮选工业化的应用现状。结果表明:氧化/低阶煤表面丰富的含氧官能团(如羧基、羟基、醚基等)以及发达的孔隙结构,使煤表面水化薄膜更稳定,煤粒与气泡的附着变得困难,浮选效果恶化。选前预处理被认为是改善浮选性能的一个重要手段。常见的预处理方法包括超声波、磨矿、热处理、高剪切调浆、压缩孔隙、药剂预先吸附、等离子体预处理等,这些方法能够通过物理和化学手段改善煤粒的表面性质,进而提高浮选效率。界面调控是氧化/低阶煤浮选技术中的另一个重要研究方向。合适的表面活性剂、浮选药剂和疏水性纳米颗粒吸附改性,能够不同程度地改善氧化/低阶煤表面的疏水性。此外,微纳米气泡浮选技术、油泡浮选技术和反浮选技术等也为改善氧化/低阶煤浮选提供了新的思路。微纳米气泡浮选技术通过提高气泡与煤粒的碰撞黏附效率,增强了煤粒的浮选效果;油泡浮选技术能够通过改变气泡的表面性质,改善其与煤粒的作用效果。然而,目前氧化/低阶煤浮选工业化应用还处于起步阶段,氧化/低阶煤浮选高效环保药剂的开发、浮选过程的稳定性等问题仍未得到彻底解决。最后,展望了氧化/低阶煤浮选技术的发展方向,在对氧化/低阶煤表面性质、结构特征精准分析的基础上,借助原位力学表征手段对药剂、气泡与氧化/低阶煤表面相互作用机制进行解析,开发高效浮选药剂实现界面性质精准调控是实现氧化/低阶煤高效浮选的必经之路。

     

    Abstract: The research progress of oxidized/low rank coal flotation technology is of great significance to improve the utilization efficiency of coal resources. An overview of the research progress on the flotation technology of oxidized/low rank coal is presented, and the fundamental reasons of the difficulty of efficient flotation of oxidized/low rank coals are explored. This can provide a basis for developing new and efficient technologies and processes for oxidized/low rank coal flotation. The surface properties analysis of oxidized/low rank coal, the research results of domestic and foreign scholars in the pretreatment of oxidized/low rank coal, optimization of flotation reagents, and enhancement of the flotation process in recent years are summarized. The current industrial application status of flotation of oxidized/low rank coal is outlined. The results showed that the increase in oxygen-containing functional groups on the surface of coal (such as carboxyl, hydroxyl, ether groups, etc.) and the developed pore structure led to the stabilization of the liquid film on the surface of oxidized/low rank coal, which makes it difficult for coal particles to attach to air bubbles, thereby deteriorating the flotation performance. Pretreatment before flotation is considered an important method to improve flotation performance. Common pretreatment methods include ultrasonic, grinding, heat treatment, high-shear slurry conditioning, compression pore, pre-adsorption of reagent, and plasma pretreatment, which can improve the surface properties of coal particles by physical and chemical means, thereby enhancing flotation efficiency. Interface modulation is another important research direction in oxidized/low rank coal flotation technology. Suitable surfactants, flotation reagents and hydrophobic nanoparticle adsorption modification can improve the hydrophobicity of oxidized/low rank coal surfaces to varying degrees. In addition, flotation methods such as micro-nano bubble flotation, oil bubble flotation, and reverse flotation technology have also provided new ideas for improving the flotation of oxidized/low rank coal. Micro-nano bubble flotation technology enhances the flotation effect of coal particles by improving the collision and adhesion efficiency between bubbles and coal particles. Oil bubble flotation technology can improve the interaction between bubbles and coal particles by altering the surface properties of the bubbles. However, the industrial application of flotation of oxidized/low rank coal is still in its infancy. The development of efficient and environmentally friendly reagents for the flotation of oxidized/low rank coal, as well as issues related to the stability of the flotation process, have not yet been completely solved. Finally, the development of oxidized/low rank coal flotation technology was reviewed. On the basis of accurate analysis of the surface properties and structural characteristics of oxidized/low rank coal, the analysis of the interaction mechanism between reagents, bubbles and oxidized/low rank coal surfaces by means of precise in-situ mechanical characterization, as well as the development of efficient flotation reagents to achieve precise control of interfacial properties, is the necessary path to realize the high-efficiency flotation of oxidized/low rank coal.

     

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