流化床中氨气燃烧特性的试验研究

Experimental study on combustion characteristics of ammonia in fluidized bed

  • 摘要: 氨气是一种具有巨大潜力的无碳清洁化学储能载体,将其作为燃料使用有望推进可再生能源的大规模应用。流化床床料颗粒的比热容较大,且可使用催化剂颗粒作为床料,这些优势有助于氨气在流化床中的着火与稳定燃烧。然而关于流化床中氨气燃烧特性以及相关操作参数对燃烧特性的影响仍不明确。搭建了高温流化床试验装置,基于试验探究了氨气在流化床中的燃烧特性,考察了当量比、稀释氧气体积分数和床层初始温度对床层温度分布、一氧化氮浓度、氨转化率以及氨逃逸浓度的影响,并且比较了预混燃烧与扩散燃烧的差异。研究结果表明,贫燃情形下,尾气中一氧化氮浓度较高;富燃情形下,尾气中一氧化氮浓度下降,床层温度下降,氨转化率下降,氨逃逸浓度随之上升。床层温度与尾气中一氧化氮浓度随氧气体积分数的上升而上升。床层初始温度下降时,稳定燃烧后的床层温度最高的区域更接近稀相区。对于扩散燃烧而言,在氨气总量不变的前提下,氧气体积分数的上升使得氨转化率有所上升。在输入气体参数完全相同的条件下,扩散燃烧与预混燃烧稳定后的床层温度、尾气中一氧化氮浓度与氨转化率并没有显著的区别。这一结果表明对于当前的试验装置与操作参数,预混燃烧或扩散燃烧对氨气在流化床内的燃烧特性不会产生显著的影响。

     

    Abstract: Ammonia is a chemical energy storage carrier with great potential, and its use as a fuel is expected to promote the large-scale application of renewable energy. Fluidized beds, characterized by their high specific heat capacity and potential use of catalyst particles, offer advantages that facilitate ammonia ignition and stable combustion. However, combustion characteristics of ammonia in fluidized beds and effects of operating parameters remain unclear. In this study, a high-temperature fluidized bed setup is constructed to investigate the combustion characteristics of ammonia. The effects of equivalence ratio, oxygen volume fraction, and initial bed temperature on temperature distribution, emissions of nitrogen monoxide (NO), ammonia conversion rate and ammonia slip concentration are examined. The differences between premixed and diffusion combustion are also compared. The results indicate that under fuel-lean combustion, NO emissions are relatively high, while under fuel-rich combustion, NO emissions decrease, bed temperature drops and ammonia conversion rate decrease, ammonia slip concentration increases accordingly. Both bed temperature and NO emissions rise with increasing oxygen volume fraction. As initial bed temperature decreases, the region with the highest bed temperature after stable combustion shifts closer to the freeboard. For diffusion combustion, at a constant total ammonia input, an increase in oxygen volume fraction leads to reduced unburned ammonia. Under identical gas input parameters, there are no significant differences in bed temperature, NO emissions and ammonia conversation rate between diffusion and premixed combustion. This suggests that combustion of ammonia in a fluidized bed are not significantly affected by whether combustion is premixed or diffusive for the current experimental setup and operating parameters.

     

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