基于固液气三废协同矿化利用的含水层结构控制保水采煤技术

Aquifer structure-controlled water-conservative coal mining technology based on coordinated mineralization of solid-liquid-gaseous three waste

  • 摘要: 煤炭开采和利用过程中带来的固(煤基固废)、液(矿井水)、气(电厂烟气)三废问题对生态造成显著影响,三废低碳处置利用是实现可持续发展目标的必然选择。围绕近零生态损害与保水开采战略目标,提出基于煤炭矿区固液气三废协同矿化利用的含水层结构控制保水采煤技术体系,利用多源煤基固废、高盐矿井水与电厂烟气协同制备CO2矿化固碳注充材料,构建了高孔隙结构注充材料,在满足强度、流动性和稳定性要求的同时有效支撑采动岩体并稳定封存CO2,实现了井下差异化场景(隔水层注浆、连采连充及采空区滞后充填等)下的保水采煤。定义了三废协同矿化利用注充保水采煤的科学内涵,构建了基于煤基固废−高盐矿井水−CO2三废协同的注充材料矿化机理与强度理论体系,包括三废矿化利用理论、负碳高效矿化材料设计与性能优化理论。阐明了三废矿化注充材料的研制机理,揭示了三废协同矿化材料固碳及稳定性机制,以及矿化注充材料疏水抗渗机制。在此基础上,研发了常温常压下三废协同矿化注充材料制备技术、三废注充材料CO2发泡矿化制备技术、三废协同矿化注充材料疏水改性强化抗渗技术。该技术体系明确了基于多源煤基固废、高盐矿井水和电厂烟气混合物的煤矿固液气三废协同矿化利用保水采煤技术路径,为推动煤炭资源开发由传统排放型向“近零生态损害、负碳排放”转型提供了解决方案,可促进实现“双碳”目标和煤炭行业绿色低碳转型。

     

    Abstract: The solid waste (coal-based solid waste), liquid waste (mine water), and gaseous waste (power plant flue gas) generated during coal mining and utilization pose significant ecological challenges. The low-carbon disposal and utilization of these three types of waste (hereafter referred to as the “three wastes”) are essential for achieving sustainable development goals. Focused on the strategic objectives of near-zero ecological damage and water-conservative mining, a water-conservative coal mining technology system is proposed. It proposes a water-conservative coal mining technology system based on aquifer structure-controlled, utilizing the coordinated mineralization of solid, liquid, and gaseous wastes in coal mining areas. The system employs multi-source coal-based solid waste, high-salinity mine water, and power plant flue gas to synergistically prepare CO2-mineralized filling materials. These materials are engineered to form high-porosity injection fillers that effectively support mining-disturbed rock masses while enabling stable CO2 sequestration, meeting the critical requirements for strength, fluidity, and stability. The technology has been successfully applied in various water-conservative coal mining scenarios, including grouting of water-resisting layers, simultaneous extraction and injection operations, and delayed backfilling of goaf areas. A scientific framework is defined for coordinated mineralization-based injection and backfilling in water-conservative mining, establishing a theoretical system for the mineralization mechanisms and strength of filling materials derived from coal-based solid waste, high-salinity mine water, and CO2. It elucidates the development mechanisms of mineralized filling materials from solid, liquid, and gaseous waste sources, reveals the carbon sequestration and stability mechanisms of synergistically mineralized materials, and clarifies the hydrophobic and anti-permeability mechanisms of mineralized backfill materials. Building on this foundation, key technologies were developed, including the preparation of three-waste synergistic mineralized filling materials under ambient conditions, CO2 foaming mineralization technology for three-waste injection and backfill materials, and hydrophobic modification techniques to enhance the impermeability of three-waste synergistic mineralized filling materials. This integrated technical system provides a clear pathway for water-conservative coal mining through the synergistic utilization of solid, liquid, and gaseous wastes, based on the combination of multi-source coal-based solid waste, high-salinity mine water, and power plant flue gas. It offers a comprehensive solution for transforming coal resource development from the traditional emission-intensive model toward a model of near-zero ecological damage and negative carbon emissions. The realization of the “dual carbon” goals is supported, and the green, low-carbon transformation of the coal industry is promoted.

     

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