肖林, 张佳为, 周建飞, 刘括. 青海石灰沟矿区克鲁克组煤中稀土元素地球化学特征[J]. 煤炭学报, 2018, 43(S2): 505-512. DOI: 10.13225/j.cnki.jccs.2018.0141
引用本文: 肖林, 张佳为, 周建飞, 刘括. 青海石灰沟矿区克鲁克组煤中稀土元素地球化学特征[J]. 煤炭学报, 2018, 43(S2): 505-512. DOI: 10.13225/j.cnki.jccs.2018.0141
XIAO Lin, ZHANG Jia-wei, ZHOU Jian-fei, LIU Kuo. Geochemistry characteristics of rare earth elements in the Keluke Formation coal from Shihuihou Area,Qinghai[J]. Journal of China Coal Society, 2018, 43(S2): 505-512. DOI: 10.13225/j.cnki.jccs.2018.0141
Citation: XIAO Lin, ZHANG Jia-wei, ZHOU Jian-fei, LIU Kuo. Geochemistry characteristics of rare earth elements in the Keluke Formation coal from Shihuihou Area,Qinghai[J]. Journal of China Coal Society, 2018, 43(S2): 505-512. DOI: 10.13225/j.cnki.jccs.2018.0141

青海石灰沟矿区克鲁克组煤中稀土元素地球化学特征

Geochemistry characteristics of rare earth elements in the Keluke Formation coal from Shihuihou Area,Qinghai

  • 摘要: 运用电感耦合等离子质谱、XRD、XRF、SEM-EDX等技术手段测试了柴达木盆地北缘克鲁克组煤的常量元素和稀土元素含量, 分析了克鲁克组煤中稀土元素含量、分布特征、赋存状态、配分模式以及指相意义。结果表明, 石灰沟克鲁克组煤中稀土元素的含量高于中国煤、世界煤和美国煤中稀土元素均值;煤中稀土元素主要以无机形式赋存, 主要来源于陆源碎屑, 部分稀土元素源于植物本身或受到微沉积环境的影响;通过对稀土元素地球化学特征参数研究发现, 该研究区煤层中轻、中型稀土明显富集, 且稀土元素与酸性沼泽水介质条件有关, 在还原条件下形成, 同时煤层中的稀土元素主要受到以玄武岩为主要源岩的陆源控制。

     

    Abstract: This paper presents the data on the mineral composition, major and rare earth elements and ytterbium (REY) in coal from the Keluke Formation in the northern margin of Qaidam Basin.The optical microscope, inductive coupling plasma mass spectrum, X-ray and XRF were applied for studying the contents, distribution characteristics, occurrence state, distribution pattern and facies significance of the major and rare earth elements.The results indicate that the content of rare earth elements is higher than that of Chinese coal, world coal and coal in the United States.The REY in the Keluke Formation's coal mainly occur in inorganic forms, mainly from terrigenous debris, and the part of rare earth elements originate from the plants or are affected by the micro-sedimentary environment.Through the study of geochemical parameters of rare earth elements, it is found that the light and medium rare earth elements are obviously enriched in the coal, and the rare earth elements in the coal seams are related to the acidic marsh water medium conditions and formed under the reducing conditions.Meanwhile, the rare earth elements in the coal seams are mainly received terrestrial control with basic igneous rock as the main source rock.

     

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