程纬华, 程海勇, 乔登攀, 李红. 基于促凝和缓凝技术的含硫充填体力学损伤调控[J]. 煤炭学报, 2019, 44(S2): 553-559. DOI: 10.13225/j.cnki.jccs.2019.0685
引用本文: 程纬华, 程海勇, 乔登攀, 李红. 基于促凝和缓凝技术的含硫充填体力学损伤调控[J]. 煤炭学报, 2019, 44(S2): 553-559. DOI: 10.13225/j.cnki.jccs.2019.0685
CHENG Weihua, CHENG Haiyong, QIAO Dengpan, LI Hong. Regulation of mechanical damage of filling body with sulfur based on coagulation and retarding technology[J]. Journal of China Coal Society, 2019, 44(S2): 553-559. DOI: 10.13225/j.cnki.jccs.2019.0685
Citation: CHENG Weihua, CHENG Haiyong, QIAO Dengpan, LI Hong. Regulation of mechanical damage of filling body with sulfur based on coagulation and retarding technology[J]. Journal of China Coal Society, 2019, 44(S2): 553-559. DOI: 10.13225/j.cnki.jccs.2019.0685

基于促凝和缓凝技术的含硫充填体力学损伤调控

Regulation of mechanical damage of filling body with sulfur based on coagulation and retarding technology

  • 摘要: 中国目前有硫铁矿山900余处,年产硫铁矿石1 320万t,硫资源在开发过程中会产生大量含硫尾砂,含硫尾砂在地表堆存时对区域生态形成严重威胁。含硫尾砂井下充填是解决地表堆存污染问题和安全问题的有效途径,但含硫尾砂制备出的充填体往往会出现开裂、破碎、强度失效等问题,含硫尾砂对充填体强度发展作用机理不清。针对高硫尾砂充填体力学性能的特殊性,通过凝结时间观测、强度测定和X射线衍射分析,对含硫充填体力学演化过程进行了定量研究。在分析高硫尾砂充填料浆的凝结特征和强度演化规律的基础上,结合硫化物致劣机理分析,提出通过改善促凝和缓凝条件优化高含硫尾砂充填体力学性能。研究结果表明,尾砂硫化物会导致充填料浆的凝结时间显著增长、强度大幅降低,并出现28 d强度劣化损伤。尾砂硫化物发生氧化反应生成酸和硫酸根离子,造成水化产物溶解,引起硫酸盐侵蚀,造成强度下降。XRD图谱显示,一定量的次生石膏和钙矾石晶体能有效填充充填体内的孔隙,有利于强度发展; 大量的次生石膏和钙矾石晶体生成,对孔隙壁产生挤压作用,造成膨胀致裂。对于高含硫尾砂充填材料,通过促凝技术使凝结时间缩短15%,充填体早期强度提高2倍,但却无法抑制后期强度劣化; 而缓凝技术可抑制C3S的水化,延缓水化产物C—S—H凝胶和氢氧化钙的生成,早期强度降低,充填体28 d强度提高35%。

     

    Abstract: There are more than 900 pyrite mines in China, producing 13.2 million tons of pyrite annually.Sulphidic tailings are produced in the development of sulfur resources.Sulphidic tailings pose a serious threat to regional ecology when they are stored on the surface.Therefore, the cemented backfill technology is an effective approach for sulphidic tailings disposal which can avoid environmental contamination and safety problems.However, the filling body prepared from sulphidic tailings often has problems of cracking, crushing and strength failure, and the mechanism of strength development of backfills using sulphidic tailings is unclear.For the special development of the mechanical performance of cemented backfill prepared from sulphidic tailings, the mechanics evolution process was quantitatively studied by means of the setting time observation, the strength measurement and X-ray diffraction analysis.On the basis of the previous results, a new way was proposed to improve the mechanical performance of sulphide-rich backfills.It is revealed from the results that with the increase of sulphide content in tailings, the setting time was extended and the compressive strength decreased, with the 28-day strength degradation damage occurred.This could be ascribed to the oxidation of sulphide in tailings, during which process acid and sulphate were produced.As a result, hydration products dissolved and sulphate attack happened, leading to strength decreases.In the XRD patterns, a certain amount of secondary gypsum and ettringite crystals can effectively fill the pores in the filling body, which is conducive to the development of strength.However, large amounts of secondary gypsum and ettringite were found, which caused high inner pressure in backfill samples, thus leading to expansion cracks.The setting time of sulphide-rich backfills could be decreased by 15% and the early strength increased by two-fold with promoting coagulation technology, but the later strength deterioration is unable to restrain.However, the retarding technology can inhibit the hydration of C3S, and the formation of hydration products C—S—H gel and calcium hydroxide is delayed, and the mid-age strength could be improved by 35%.

     

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