王勇, 孟巧荣, 高力, 张永锋. 热解无烟煤微细观孔裂隙结构随温度的演化规律[J]. 煤炭学报, 2020, 45(S1): 300-307. DOI: 10.13225/j.cnki.jccs.2020.0088
引用本文: 王勇, 孟巧荣, 高力, 张永锋. 热解无烟煤微细观孔裂隙结构随温度的演化规律[J]. 煤炭学报, 2020, 45(S1): 300-307. DOI: 10.13225/j.cnki.jccs.2020.0088
WANG Yong, MENG Qiaorong, GAO Li, ZHANG Yongfeng. Evolution law of micro-meso pore-fracture structure of anthracite in pyrolysis[J]. Journal of China Coal Society, 2020, 45(S1): 300-307. DOI: 10.13225/j.cnki.jccs.2020.0088
Citation: WANG Yong, MENG Qiaorong, GAO Li, ZHANG Yongfeng. Evolution law of micro-meso pore-fracture structure of anthracite in pyrolysis[J]. Journal of China Coal Society, 2020, 45(S1): 300-307. DOI: 10.13225/j.cnki.jccs.2020.0088

热解无烟煤微细观孔裂隙结构随温度的演化规律

Evolution law of micro-meso pore-fracture structure of anthracite in pyrolysis

  • 摘要: 基于高精度显微CT技术,对不同温度条件下φ7 mm×10 mm晋城无烟煤的微细观孔裂隙结构的演化规律进行研究,通过MATLAB与AVIZO相结合对孔裂隙进行三维重构,并对其三维孔裂隙特征参数进行定量分析研究,结果表明:晋城无烟煤在常温到600℃的低温热解条件下,①温度低于200℃时,在热破裂的作用下,孔裂隙结构缓慢变化;200℃后无烟煤发生热解,孔径大于1 000 μm的裂隙数量先增加后减少,单条裂隙的最大直径和体积逐渐增加。300℃时,裂隙数量最多,温度达到600℃时,裂隙相互搭接连通,裂隙数量最少,单条裂隙直径最大,体积最大,裂隙发育贯通,连通性最好。②随着温度的升高,晋城无烟煤孔隙度呈上升趋势,100 ~200℃和400 ~600℃,孔隙度增加较快;分形维数呈现3个阶段,常温~300℃分形维数快速增大,300 ~500℃缓慢减小,500~600℃又增大。③300℃是无烟煤低温热解过程中的一个转折温度,该温度,大裂隙相互贯通,孔隙度为36.7%,孔裂隙的表面积分形维数达到最大2.236,渗透性已经达到完全渗透的指标,所以,对于无烟煤来说,注热增渗可以考虑加热到300℃。

     

    Abstract: Through the high-precision micro CT technology,the evolution law of micro pore fracture structure of Jincheng Anthracite samples with diameter of 7 mm and length of 10 mm under different temperature conditions is studied. The 3D reconstruction of pore fracture is carried out through MATLAB and Avizo,and the 3D characteristic parameters of pore fracture are quantitatively analyzed. The study results on Jincheng Anthracite show that during a low temperature pyrolysis from room temperature to 600℃,① When the temperature is below 200℃,the pore fracture structure changes slowly under the action of thermal cracking; at over 200℃,the pyrolysis of anthracite occurs,the number of fractures with a diameter greater than 1 000 μm increases first and then decreases,and the maximum diameter and volume of fractures increase gradually. At 300℃,the number of fractures reaches the maximum number.When the temperature reaches 600℃,the fractures are overlapped and connected with each other,the number of fractures is the least,the diameter of a fracture is the largest and its volume is the largest,the connectivity is the best.②With the increase of temperature,the porosity of Jincheng Anthracite shows an upward trend,and the porosity in-creases rapidly at from 100℃ to 200℃ and from 400℃ to 600℃ separately; the fractal dimension shows three stages:the fractal dimension increases rapidly from room temperature to 300℃,and decreases slowly from 300℃ to 500℃,then increases again from 500℃ to 600℃. ③ The 300℃ is a key temperature in the process of low-temperature pyrolysis of anthracite. At this temperature,the large fractures are formed,the porosity is 36.7%,the fractal dimension of the surface area of the pores and fractures is up to 2.236,and the permeability has reached the index of complete permeability. Therefore,for anthracite,the 300℃can be the temperature of heat injection to increase permeability.

     

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