张建俊, 姚柏聪, 孙源骏, 刘晓龙, 王宝强, 梁世纪, 林增华, 刘静. 离子固化剂对水泥稳定煤矸石结合料耐久性能的影响[J]. 煤炭学报, 2022, 47(9): 3472-3482. DOI: 10.13225/j.cnki.jccs.2022.0674
引用本文: 张建俊, 姚柏聪, 孙源骏, 刘晓龙, 王宝强, 梁世纪, 林增华, 刘静. 离子固化剂对水泥稳定煤矸石结合料耐久性能的影响[J]. 煤炭学报, 2022, 47(9): 3472-3482. DOI: 10.13225/j.cnki.jccs.2022.0674
ZHANG Jian-jun, YAO Bo-cong, SUN Yuan-jun, LIU Xiao-long, WANG Bao-qiang, LIANG Shi-ji, LIN Zeng-hua, LIU Jing. Effect of ionic stabilizer on the durability performance of cement stabilized gangue bonding material[J]. Journal of China Coal Society, 2022, 47(9): 3472-3482. DOI: 10.13225/j.cnki.jccs.2022.0674
Citation: ZHANG Jian-jun, YAO Bo-cong, SUN Yuan-jun, LIU Xiao-long, WANG Bao-qiang, LIANG Shi-ji, LIN Zeng-hua, LIU Jing. Effect of ionic stabilizer on the durability performance of cement stabilized gangue bonding material[J]. Journal of China Coal Society, 2022, 47(9): 3472-3482. DOI: 10.13225/j.cnki.jccs.2022.0674

离子固化剂对水泥稳定煤矸石结合料耐久性能的影响

Effect of ionic stabilizer on the durability performance of cement stabilized gangue bonding material

  • 摘要: 水泥稳定煤矸石结合料用于寒区道路工程极易发生冻害,适量添加固化剂是增强其路用耐久性能的重要途径。通过7 d无侧限抗压强度试验、温缩试验、渗水试验、抗冲刷试验、冻融试验,分别研究离子型煤矸石固化剂(ICG)掺量(0,0.005%,0.010%,0.015%,0.020%)对水泥稳定煤矸石结合料(CS)的强度与耐久性的影响,通过压汞试验(MIP)、X射线衍射(XRD)、傅里叶红外光谱仪(FTIR)及热重-微商热重联合法(TG-DTG),分析ICG对CS的孔隙结构与水化产物的影响,并对作用机理进行了探究。此外,基于压汞试验数据,研究了ICG固化CS孔隙结构的分形特征,构建了分形维数Ds与CS耐久性之间的联系。结果表明:CS掺入ICG后,弱结合水转变为自由水,同时水溶液中Ca2+浓度增加,促进了水化产物的生成,孔隙结构复杂化,Ds增大,孔隙体积缩小,孔隙率降低,CS孔隙结构密闭性增加,进而提高了CS的抗压强度、抗温缩性能、抗渗性能、抗冲刷性能及抗冻性能,从而提高CS的耐久性能,当ICG掺量为0.010%时,ICG的固化效果最显著。此外,分形维数Ds与CS的耐久性参数之间存在线性关系,因此Ds可以作为评价水泥稳定煤矸石结合料耐久性的一个新参数。研究成果可为离子固化剂应用于水泥稳定煤矸石结合料中提供一定的参考。

     

    Abstract: Cement-stabilized gangue bonding material for road projects in cold areas is very susceptible to frost damage. The appropriate amount of added stabilizer is an important way to enhance its road durability performance.The effects of ionic gangue stabilization( ICG) admixture(0,0.005%,0.010%,0.015%,0.020%) on the strength and durability of cement-stabilized gangue bonding material(CS) were studied through 7 d unconfined compressive strength test,temperature shrinkage test,water penetration test,scouring test and freeze-thaw test,respectively. Using mercury-pressure test(MIP),X-ray diffraction(XRD),Fourier infrared spectroscopy(FTIR) and combined thermogravimetric-micro-commercial thermogravimetric method(TG-DTG),the effect of ICG on the pore structure and hydration products of CS,and their action mechanism were analyzed. In addition,the fractal characteristics of the pore structure of ICG-stabilized CS were investigated based on the data of the mercury-pressure test, and the link between the fractal dimension Ds and the durability of CS was constructed. The results showed that after CS was mixed with ICG,the weakly bound water was transformed into free water,while the Ca2+ concentration in the aqueous solution increased,which promoted the generation of hydration products,and pore structure complexity. Also,it made the value of Ds increase, the pore volume decrease, the porosity decrease, and the CS pore structure confinement increase.In turn,it improved the compressive strength,temperature shrinkage resistance,seepage resistance,scour resistance,and frost resistance of CS,thus,improving the CS durability performance. The stabilization effect of ICG was most significant when the ICG doping amount was 0.010%. In addition,there was a linear relationship between the fractal dimensionDsand the durability parameters of CS,so Ds could be used as a new parameter to evaluate the durability of cement-stabilized gangue binders. The research results can provide some references for the application of ionic stabilizers in cement-stabilized gangue binding materials.

     

/

返回文章
返回